Go through these in order and stop at the first one that applies. If you are reading this for someone else, answer for them.
Call emergency services for severe breathing difficulty, a seizure, collapse, loss of consciousness, or marked confusion.
Do not attempt a rescue in an enclosed or contaminated space unless trained and properly equipped.
And for anyone, someone who:
Seek prompt medical care for fever, new unexplained bruising, ongoing nosebleeds, unusual weakness, or worsening cough after an exposure.
These symptoms are not always caused by benzene, but they should be assessed.
Follow-up depends on the amount and duration of exposure, symptoms, and initial test results.
A brief, low-level exposure without symptoms may need only poison-center or clinician guidance.
A significant exposure may require repeat examinations and blood counts, even if the person initially feels well.
Arrange routine medical follow-up if symptoms such as fatigue, easy bruising, recurrent infections, or skin irritation continue.
Follow the recommended schedule for repeat blood tests rather than assuming that one normal result rules out all later effects.
The article also says
Keep a record of the date, location, product, estimated duration, symptoms, and names of witnesses.
Workplace air-monitoring results and safety data sheets may also be useful.
Workers should report suspected exposure through their employer's safety or occupational health process.
Every sign above is quoted from the sofidex article on Benzene poisoning. If you are not sure, err upward — it is always reasonable to be checked.